The application of 7H-indolo[1,2-a]quinolinium merocyanine as a new water sensor in organic solvents
نویسندگان
چکیده
Abstract The 7H-indolo[1,2-a]quinolinium merocyanine was applied as a new water sensor in organic solvents such as ethanol, propane-1-ol, propane-2-ol, DMSO, and DMF. The spectral changes of the dye caused by the addition of increasing amount of water into an organic solvent were investigated. Based on the results, the calibration curves were found as a relation between the position of the absorption band of the dye and the water concentration ranging from about 0.05 to 11% (w/w). In case of ethanol, propane-1-ol and propane-2-ol the plots were linear, whereas in DMSO and DMF, better results were obtained with the use of a polynomial function. The method allowed to determine the water content in a fast and precise manner. Graphical Abstract
منابع مشابه
Disposable single-use electrochemical sensor: A novel hollow fiber based tool for environmental monitoring of cadmium
The objective of this study is to design a simple, fast, sensitive and single-use electrode with the simultaneous capability of preconcentration and measuring, for application in a three-electrode voltammetry system to identify and measure the heavy metal cadmium. The design process of this sensor consists of several stages. The polyurethane foam and multi walled carbon nanotubes nanoparticles ...
متن کاملApplication of Water for Synthesis of Cyclopentadienes via Multi-component Reactions of N-methyl imidazole
A water-accelerated multi-component synthesis of organic target molecules was used as a key method for the preparation of cyclopentadiene derivatives. The three-component condensation reactions of primary amines with alkyl propiolates in the presence of N-methylimidazole in water at room temperature were developed as efficient and clean green synthetic procedures for the high-yielding preparati...
متن کاملPrediction of the pharmaceutical solubility in water and organic solvents via different soft computing models
Solubility data of solid in aqueous and different organic solvents are very important physicochemical properties considered in the design of the industrial processes and the theoretical studies. In this study, experimental solubility data of 666 pharmaceutical compounds in water and 712 pharmaceutical compounds in organic solvents were collected from different sources. Three different artificia...
متن کاملTrans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane/HOAc/KI system as a new and mild catalyst for efficient synthesis of 1H-benzimidazoles and 1H-benzothiazoles in water
An efficient method has been developed for the catalysis of condensation of 1,2-phenylenediamines and 2-aminothiophenoles with different aldehydes into their corresponding 2-aryl-1H-benzimidazoles and 2-aryl-1H-benzothiazoles under mild condition. In this method, trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane (DHPDMDO)/HOAc/KI system was used as a novel and effective oxidant in water at roo...
متن کاملA simplified green approach for synthesis of arylquinoxalines under solvent-free clay-catalysed conditions
A friendly benign, green, rapid and facile strategy for synthesis a series of arylquinoxalines was achieved by condensation of aromatic 1,2-diamines with arylglyoxals under clay-catalyzed as an inexpensive and eco-friendly catalyst using grindstone chemistry. Significant decreases in reaction times and high yields have been observed by this green chemistry approach in comparison with previously...
متن کامل